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Thermal expansion coefficients (CTE).

Linear coefficient of thermal expansion for the engineering materials in this reference, sorted from lowest CTE (Invar) to highest (engineering plastics). Use it for thermal-stack calculations, optical mount stability, cryogenic dimensional shift, and dissimilar-metal-fit analysis.

Materials
32
Lowest CTE
Invar 36
1.3 ppm/°C
Highest metal
Magnesium
26 ppm/°C
Reference temp
20–100 °C

By value, ascending

Sorted from lowest expansion to highest.

CTE values in parts per million per degree (ppm/°C and ppm/°F). For typical 20–100 °C reference range. Note: CTE varies modestly with temperature — for cryogenic or high-temperature applications, look up the CTE at your operating range, not just at room temperature.

MaterialFamilyCTE (ppm/°C)CTE (ppm/°F)
Invar 36(20–100 °C)Low-CTE alloy1.30.7
Tungsten (W)Refractory metal4.52.5
Tantalum (Ta)Refractory metal6.53.6
Niobium (Nb)Refractory metal7.34.1
Titanium Ti-6Al-4VTitanium alloy8.64.8
Titanium CP Grade 2Pure titanium8.64.8
Stainless 410Martensitic stainless9.95.5
Tool steel H13Tool steel10.45.8
Tool steel D2Tool steel10.65.9
Tool steel A2Tool steel10.65.9
Stainless 17-4PHPH stainless10.86
Hastelloy C-276Nickel superalloy11.26.2
Steel 1018 (mild)Carbon steel11.76.5
Steel 4140Alloy steel12.26.8
Steel 4340Alloy steel12.26.8
Inconel 625Nickel superalloy12.87.1
Inconel 718Nickel superalloy137.2
Monel 400Nickel alloy13.97.7
Stainless 316LAustenitic stainless168.9
Copper C110 (ETP)Pure copper16.99.4
Stainless 304Austenitic stainless17.39.6
Beryllium copper C172Cu-Be alloy17.89.9
Bronze C932Bearing bronze1810
Brass C360Free-machining brass20.511.4
MIC-6 cast aluminumCast aluminum plate2312.8
Aluminum 2024-T3Aerospace aluminum23.212.9
Aluminum 6061-T6Aluminum23.613.1
Aluminum 7075-T6Aerospace aluminum23.613.1
Magnesium AZ31Magnesium25.914.4
PEEK(below Tg)Engineering plastic4726.1
Ultem (PEI)Engineering plastic5228.9
Delrin / POMEngineering plastic11061.1

Why this matters

Thermal stack-up arithmetic.

  • A 12″ aluminum part swings 0.016″ over a 100°F change.

    12 in × 13.1 ppm/°F × 100°F = 0.0157″. Multiply that by the number of dissimilar-metal interfaces in your assembly and you can see why aerospace optical-bench designs lean hard on Invar.

  • Dissimilar metals: subtract the CTEs.

    A bushing pressed in an aluminum housing using a titanium pin — Δ CTE = 23.6 − 8.6 = 15 ppm/°C. Over a 60°C swing on a 25 mm bushing: 25 × 15 × 60 / 1,000,000 = 0.023 mm of differential. Either accept it, design clearance for it, or pick same-CTE materials.

  • Cryogenic CTE is not the room-temp value.

    Most metals contract more slowly per degree at very low temperatures. For 4 K and 77 K dimensional analysis (cryostat hardware, superconducting magnets), use cryogenic-specific contraction data — it’s not a linear extrapolation from 20 °C values.

  • Plastics expand 3–4× more than metals.

    Delrin (POM) at 110 ppm/°C will move >0.001″ per inch per 10 °C. For tight-tolerance plastic features, design with thermal expansion explicitly in the calculation — and consider PEEK (47 ppm/°C) for tighter applications.

  • Match the CTE for sensitive optical/sensor work.

    Mounting an Invar-grade structure to an aluminum baseplate creates massive thermal stresses. For optical benches, sensor mounts, and dimensional-stability hardware, match CTE within ~3 ppm or accept the consequences.

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